It's been announced that he will defend the title against Randy Orton at Extreme Rules, although I can easily see the match being made into a triple threat match including Roman Reigns. Either way I see 4 straight PPVs with Rollins defending the championship against Orton and Reigns at Extreme Rules, Payback, Money in the Bank and Battleground, most likely with street fight, ladder and steel cage stipulations (WWE is usually predictable leading up to SummerSlam, as we've seen the last two years).
Technically Brock Lesnar is entitled to the rematch, but he was "suspended" so he likely won't return until SummerSlam to challenge for the championship.
Roman Reigns
Orton or Reigns. It could turn out to be both, making it a triple-threat match.
I've also heard that Ryback could be added to the match, making it a Fatal-4-Way match as the main event at Extreme Rules.
Either Randy Orton, Roman Reigns, or both
Randy Orton has been confirmed.